Kefauver S.C., Filella I., Zhang C., Penuelas J. (2015) Linking OMI HCHO and MODIS PRI satellite data with BVOCS emissions in NE Spain. International Geoscience and Remote Sensing Symposium (IGARSS). 2015-November: 2661-2664.LinkDoi: 10.1109/IGARSS.2015.7326360
Volatile organic compounds (VOCs) play several important roles on tropospheric chemical composition. Biogenic VOCs (BVOCs) are the largest source of NMVOCs (non-methane VOCs), accounting for the release of up to 10% of total C fixed by plants in photosynthesis. As isoprene is often the dominant source of atmospheric formaldehyde (HCHO) detected using satellite sensors, it is often correlated directly to satellite HCHO observations without accounting for other HCHO sources. Here we investigate the importance of quantifying monoterpene emissions when linking remotely sensed HCHO vertical columns to terrestrial BVOCs emissions at four different ecosystems in NE Spain where monoterpene-isoprene emissions ratios are known to be unusually high. Average HCHO yield for present monoterpenes was approximately 29% compared to 45% for isoprene. Including monoterpene HCHO yield contributions in total atmospheric HCHO concentrations improved correlations from R2 of 0.35 to 0.66 and R2 of 0.56 to 0.89 when comparing OMI HCHO and MODIS PRI satellite with HCHO field measurements, respectively. © 2015 IEEE.
Kefauver S.C., Filella I., Penuelas J. (2014) Remote sensing of atmospheric biogenic volatile organic compounds (BVOCs) via satellite-based formaldehyde vertical column assessments. International Journal of Remote Sensing. 35: 7519-7542.LinkDoi: 10.1080/01431161.2014.968690
Global vegetation is intrinsically linked to atmospheric chemistry and climate, and better understanding vegetation–atmosphere interactions can allow scientists to not only predict future change patterns, but also to suggest future policies and adaptations to mediate vegetation feedbacks with atmospheric chemistry and climate. Improving global and regional estimates of biogenic volatile organic compound (BVOCs) emissions is of great interest for their biological and environmental effects and possible positive and negative feedbacks related to climate change and other vectors of global change. Multiple studies indicate that BVOCs are on the rise, and with near 20 years of global remote sensing of formaldehyde (HCHO), the immediate and dominant BVOC atmospheric oxidation product, the accurate and quantitative linkage of BVOCs with plant ecology, atmospheric chemistry, and climate change is of increasing relevance. The remote sensing of BVOCs, via HCHO in a three step process, suffers from an additive modelling error, but improvements in each of the steps have reduced this error by over a multiplication factor improvement compared to estimates without remote sensing. Differential optical absorption spectroscopy (DOAS) measurement of the HCHO slant columns from spectral absorption properties has been adapted to include the correction of numerous spectral artefacts and intricately refined for each of a series of sensors of increasing spectral and spatial resolution. Conversion of HCHO slant to HCHO vertical columns using air mass factors (AMFs) has been improved with the launch of new sensors and the incorporation of radiative transfer and chemical transport models (CTM). The critical process of linking HCHO to BVOC emissions and filtering non-biogenic emissions to explicitly quantify biogenic emissions has also greatly improved. This critical last step in down-scaling from global satellite coverage to local biogenic emissions now benefits from the increasing precision and near-explicitness of available CTMs as well as the increasing availability of global remote-sensing data sets needed to proportionally assign the HCHO column to different related biogenic (global plant functional type and land cover classifications), atmospheric (dust, aerosols, clouds, other trace gases), climate (temperature, wind, precipitation), and anthropogenic (fire, biomass burning) factors.
Peñuelas J, Filella I, Estiarte M, Ogaya R, Llusià J, Sardans J, Jump A, Carnicer J, Rico L, Garbulsky M, Coll M, Díaz de Quijano M, Seco R, Rivas-Ubach A, Kefauver S, Barbeta A, Achoategui A, Mejía-Chang M, Gallardo A, Farre G, Fernández M, Terradas J (2012) Ecosystemic and biospheric interactions with carbon cycle. In Carbon dioxide budget: processes and tendencies symposium. Universitat Politècnica de Catalunya, May 23-25.
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