Muhs DR, Budahn J, Avila A, Skipp G, Freeman J, Patterson D (2010) The role of African dust in the formation of Quaternary soils on Mallorca, Spain and implications for the genesis of Red Mediterranean soils. Quaternary Science Reviews 29: 2518-2543. doi:10.1016/j.quascirev.2010.04.013.
Avila A., Molowny-Horas R., Gimeno B.S., Peñuelas J. (2010) Analysis of decadal time series in wet N concentrations at five rural sites in NE Spain. Water, Air, and Soil Pollution. 207: 123-138.EnllaçDoi: 10.1007/s11270-009-0124-7
Nitrogen emissions have grown in Spain during the last 15 years. As precipitation scavenges gases and aerosols from the atmosphere, an effect on rainwater concentrations can be expected. However, time-series studies on wet N concentrations in the Iberian Peninsula are very scarce. This paper aims to fill this gap by analysing weekly rainfall N concentrations at a set of rural sites in Catalonia (NE Spain) from 1995/1996 to 2007 and a forest site monitored from 1983 to 2007. The sites encompass a range of rural environments and climate conditions, from the inland pre-Pyrenees (Sort) to the Mediterranean coast (Begur) and from north (Sort and Begur) to central (Palautordera and La Castanya) and south Catalonia (La Senia). We found a 1-year cycle for concentrations of NH 4 + and NO 3 - whereby higher values were reached at the end of spring-early summer, except at the easternmost coastal site of Begur. Weekly NH 4 + concentrations decreased with time at all sites (except at La Senia) whilst NO 3 - concentrations increased at all sites during the same period. Rainfall SO 4 2- concentrations decreased with time at all sites. The opposite trends in NO 3 - and SO 4 2- concentrations determined a shift in the relative acid contribution of those anions during the 12-13-year period. To interpret the increasing trend, mean annual NO 3 - concentrations were regressed against NO 2 Spanish emissions and to some indicators of local anthropogenic activity. The increase at Sort and Palautordera showed good correlation with local anthropogenic indicators. Wet inorganic N deposition ranged between 4.2 and 6.7 kg ha -1 year -1. When including estimates of dry deposition, total annual deposition rose up to 10-20 kg ha -1 year -1, values that have been found to initiate adverse effects on Mediterranean-type forest ecosystems. © 2009 Springer Science+Business Media B.V.
Domene X., Colón J., Uras M.V., Izquierdo R., Àvila A., Alcañiz J.M. (2010) Role of soil properties in sewage sludge toxicity to soil collembolans. Soil Biology and Biochemistry. 42: 1982-1990.EnllaçDoi: 10.1016/j.soilbio.2010.07.019
Soil properties are one of the most important factors explaining the different toxicity results found in different soils. Although there is knowledge about the role of soil properties on the toxicity of individual chemicals, not much is known about its relevance for sewage sludge amendments. In particular little is known about the effect of soil properties on the toxicity modulation of these complex wastes. In addition, in most studies on sewage sludges the identity of the main substances linked to the toxicity and the influence of soil properties on their bioavailability remains unknown.In this study, the toxicity of a sewage sludge to the soil collembolan Folsomia candida was assessed in nine natural soils from agricultural, grassland and woodland sites, together with the OECD soil. Correlations between the relative toxicity of sludge for collembolans in the different soils and their physical and chemical soil properties were assessed in order to identify the main compounds responsible for the effects observed. Furthermore, the relationships between the toxic effects to collembolans and water-soluble ions released by sludge, pH and electric conductivity were also assessed, together with the modulating effects of soil properties.Sludge toxicity was directly linked to the water extractable ammonium, which explained most of the mortality of the collembolans, and part of the inhibition of reproduction. For the last endpoint, nitrite also contributed significantly to the inhibition observed. The varied levels in water extractable ammonium in the different soils at equal dosages seem to be, in turn, modulated by some soil properties. Higher organic carbon contents were associated with lower toxicity of sludge, both for survival and reproduction, probably related to its higher ammonium sorption capacity. In addition, for reproduction, increasing the C/N ratio and pH appeared to increase the toxicity, probably due to both the greater difficultly in nitrification and the known unsuitability of alkaline soils for this species. © 2010 Elsevier Ltd.
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